Programs include sensors, cancer research, chemical education, environmental chemistry, sustainable chemistry, reactive intermediates, polymer chemistry, computational chemistry, nanoscale science, materials chemistry and more.

Faculty may submit research here.

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Submissions from 2011

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Controls over soil microbial biomass responses to carbon amendments in agricultural systems: A meta-analysis, Cynthia M. Kallenbach and A. Stuart Grandy

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Tandem Chain Extension-Aldol Reaction Used for Synthesis of Stabilized Ketomethylene Prodrugs Targeting hPEPT1, Karina Thorn, Carsten Uhd Nielsen, Palle Jakobsen, Bente Steffansen, Charles K. Zercher, and Mikael Begtrup

Submissions from 2010

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A comparison of GC-FID and PTR-MS toluene measurements in ambient air under conditions of enhanced monoterpene loading, Jesse L. Ambrose, K. Haase, R. S. Russo, Y. Zhou, M. L. White, E. K. Frinak, C. Jordan, Howard R. Mayne, Robert W. Talbot, and B. C. Sive

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The Chemical Composition of Rainfall and Throughfall in Five Forest Communities: A Case Study in Fort Benning, Georgia, Shirish Bhat, Jennifer M. Jacobs, and Malcolm L. Bryant

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2,3-Bis(bromomethyl)-1,4-diphenylbenzene, Jonathan B. Briggs, Mikael D. Jazdzyk, and Glen P. Miller

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A Mechanistic Investigation into the Zinc Carbenoid-mediated Homologation Reaction by DFT methods: Is a Classical Donor-Acceptor Cyclopropane Intermediate Involved?, Wilhelm A. Eger, Charles K. Zercher, and Craig M. Williams

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Advocates, agendas, and nay-sayers: science and technology in the public arena, Arthur Greenberg

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Thinking outside the channel: modeling nitrogen cycling in networked river ecosystems, Ashley M. Helton, Geoffrey C. Poole, Judy L. Meyer, Wilfred M. Wollheim, Bruce J. Peterson, Patrick J. Mulholland, Emily S. Bernhardt, Jack A. Stanford, Clay Arango, Lee W. Cooper, Walter K. Dodds, Stanley V. Gregory, Robert O. Hall Jr., Stephen K. Hamilton, Sherri L. Johnson, William H. McDowell, Jody D. Potter, Jennifer L. Tank, Suzanne M. Thomas, H. Maurice Valett, Jackson R. Webster, and Lydia Zeglin

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NMR and XAS reveal an inner-sphere metal binding site in the P4 helix of the metallo-ribozyme ribonuclease P, Kristin S. Koutmou, Anette Casiano-Negroni, Melissa M. Getz, Samuel Pazicni, Andrew J. Andrews, James E. Penner-Hahn, Hashim M. Al-Hashimi, and Carol A. Fierke

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Sedimentation, Thomas M. Laue

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Interactions Between Land Cover/Use Change and Hydrology, Alexander I. Shiklomanov, Theodore J. Bohn, Dennis P. Lettenmaier, Richard B. Lammers, Peter Romanov, Michael A. Rawlins, and Jennifer C. Adam

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The oribatid mite Scheloribates moestus (Acari: Oribatida) alters litter chemistry and nutrient cycling during decomposition, Kyle Wickings and A. Stuart Grandy

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Management intensity alters decomposition via biological pathways, Kyle Wickings, A. Stuart Grandy, Sasha Reed, and Cory Cleveland

Submissions from 2009

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1,2-Dimethyl-4,5-diphenylbenzene determined on a Bruker SMART X2S benchtop crystallographic system, Jonathan B. Briggs, Mikael D. Jazdzyk, and Glen P. Miller

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2,5-Dichlorothiophene 1,1-dioxide, Jonathan B. Briggs, Wenling Jia, Mikael D. Jazdzyk, and Glen P. Miller

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Coencapsulation of arsenic- and platinum-based drugs for targeted cancer treatment, Haimei Chen, Samuel Pazicni, Nancy L. Krett, Richard W. Ahn, James E. Penner-Hahn, Steven T. Rosen, and Thomas V. O'Halloran

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The influence of microbial communities, management, and soil texture on soil organic matter chemistry, A. Stuart Grandy, Michael S. Strickland, Christian L. Lauber, Mark A. Bradford, and Noah Fierer

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Characterizing canopy biochemistry from imaging spectroscopy and its application to ecosystem studies, Raymond F. Kokaly, Gregory P. Asner, Scott V. Ollinger, Mary E. Martin, and Carol A. Wessman

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Stereoselective Formation of a Functionalized Dipeptide Isostere by Zinc Carbenoid-mediated Chain Extension, Weimin Lin, Cory R. Theberge, Timothy J. Henderson, Charles K. Zercher, Jerry P. Jasinski, and Ray J. Butcher

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The interaction of mitochondrial iron with superoxide dismutase, Amornrat Naranuntarat, Laran T. Jensen, Samuel Pazicni, James E. Penner-Hahn, and Valeria C. Culotta

Submissions from 2008

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Molecular C dynamics downstream: The biochemical decomposition sequence and its impact on soil organic matter structure and function, A. Stuart Grandy and Jason C. Neff

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Nitrogen deposition effects on soil organic matter chemistry are linked to variation in enzymes, ecosystems and size fractions, A. Stuart Grandy, Robert L. Sinsabaugh, Jason C. Neff, Martina Stursova, and Donald R. Zak

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Formation of γ-Lactones through CAN-Mediated Oxidative Cleavage of Hemiketals, Alexander M. Jacobine, Weimin Lin, Bethany Walls, and Charles K. Zercher

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Tandem Chain Extension–Iodomethylation Reactions: Formation of α-Functionalized γ-Keto Carbonyls, Qinglin Pu, Emerald Wilson, and Charles K. Zercher

Submissions from 2007

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Ferrous human cystathionine b-synthase loses activity during enzyme assay due to a ligand switch process, Melisa M. Cherney, Samuel Pazicni, Nina Frank, Katherine A. Marvin, Jan P. Kraus, and Judith N. Burstyn

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Carbon structure and enzyme activities in alpine and forest ecosystems, A. Stuart Grandy, Jason C. Neff, and Michael N. Weintraub

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Inorganic chlorine and bromine in coastal New England air during summer, William C. Keene, Jochen Stutz, Alexander A. P. Pszenny, John R. Maben, Emily V. Fischer, Allen M. Smith, Roland von Glasow, Susanne Pechtl, Barkley C. Sive, and Ruth K. Varner

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Formation of β-Substituted γ-Keto Esters via Zinc Carbenoid-Mediated Chain Extension, Weimin Lin, Robert J. McGinness, Emerald C. Wilson, and Charles K. Zercher

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Formal Synthesis of (+)-Brefeldin A: Application of a Zinc-mediated Ring Expansion Reaction, Weimin Lin and Charles K. Zercher

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Nanoparticle growth following photochemical α‐ and β‐pinene oxidation at Appledore Island during International Consortium for Research on Transport and Transformation/Chemistry of Halogens at the Isles of Shoals 2004, L. M. Russell, A. A. Mensah, Emily V. Fischer, Barkley C. Sive, Ruth K. Varner, William C. Keene, Jochen Stutz, and Alexander A. P. Pszenny

Submissions from 2006

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Relationships between stream water chemistry and military land use in forested watersheds in Fort Benning, Georgia, Shirish Bhat, Jennifer M. Jacobs, Kirk Hatfield, and Joseph Prenger

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Stereocontrolled Formation of Ketomethylene Isosteres through Tandem Chain Extension Reactions, Weimin Lin, Nancy Tryder, Fan Su, Charles K. Zercher, Jerry P. Jasinski, and Ray J. Butcher

Submissions from 2005

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Fluorescence-Dip Infrared Spectroscopy and Predissociation Dynamics of OH A (v=4) Radicals, Erika L. Derro, Ilana B. Pollack, Logan P. Dempsey, Margaret E. Greenslade, Yuxiu Lei, Dragana C. Radenovic, and Marsha I. Lester

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(2+1) Resonance Enhanced Ionization Spectroscopy of a State Selected Beam of OH Radicals, Margaret E. Greenslade, Marsha I. Lester, Dragana C. Radenovic, Andre J.A. van Roij, and David H. Parker

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Progress toward automated metabolic profiling of human serum: Comparison of CPMG and gradient-filtered NMR analytical methods, Laura H. Lucas, Cynthia K. Larive, Patricia Stone Wilkinson, and Stephen Huhn

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The heme of cystathionine b-synthase likely undergoes a temperature-induced redox-mediated ligand switch, Samuel Pazicni, Melisa M. Cherney, Gudrun S. Lukat-Rodgers, Jana Oliveriusova, Kenton R. Rodgers, Jan P. Kraus, and Judith N. Burstyn

Submissions from 2004

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Responses to Changing Needs in U.S. Doctoral Education., Marjorie Caserio, Anne K. Bentley, Matthew D. Bowman, Andrew Neal Mangham, Kevin M. Metz, Samuel Pazicni, Margaret F. Phillips, Brian P. Coppola, and Robert L. Lichter

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Reponses to Changing Needs in U.S. Doctoral Education, Marjorie Caserio, Anne K. Bentley, Matthew D. Bowman, Andrew Neal Mangham, Kevin M. Metz, Samuel Pazicni, Margaret F. Phillips, Brian P. Coppola, Jeffrey I. Seeman, and Robert L. Lichter

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Infrared spectrum and stability of a π-type hydrogen-bonded complex between the OH and C2H2 reactants, James B. Davey, Margaret E. Greenslade, Mark D. Marshall, Marsha I. Lester, and Martyn D. Wheeler

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Evidence for partial quenching of orbital angular momentum upon complex formation in the infrared spectrum of OH-acetylene, Mark D. Marshall, James B. Davey, Margaret E. Greenslade, and Marsha I. Lester

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The redox behavior of heme in cystathionine β-synthase is pH dependent, Samuel Pazicni, Gudrun S. Lukat-Rodgers, Jana Oliveriusova, Katherine A. Rees, Ryan B. Parks, Robert W. Clark, Jan P. Kraus, Judith N. Burstyn, and Kenton R. Rodgers

Submissions from 2003

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Is Nitrogen Deposition Altering the Nitrogen Status of Northeastern Forests?, John D. Aber, Christine L. Goodale, Scott V. Ollinger, Marie-Louise Smith, Alison H. Magill, Mary E. Martin, Richard A. Hallett, and John L. Stoddard

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Prediction of eucalypt foliage nitrogen content from satellite-derived hyperspectral data, Nicholas C. Coops, Marie-Louise Smith, Mary E. Martin, and Scott V. Ollinger

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Photodissociation of the OD radical at 226 and 243 nm, Dragana C. Radenovic, Andre J.A. van Roij, Dmitri A. Chestakov, Andre T.J.B. Eppink, J J. ter Meulen, David H. Parker, Mark P.J. van der Loo, Gerrit G. Groenenboom, Margaret E. Greenslade, and Marsha I. Lester

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Ring Expansions of β-Keto Lactones with Zinc Carbenoids: Synthesis of (+)-Patulolide A, Matthew D. Ronsheim and Charles K. Zercher

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Zinc Carbenoid-mediated Chain Extension: Preparation of α,β-Unsaturated-γ-Keto Esters and Amides, Matthew D. Ronsheim and Charles K. Zercher

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Chain Extension of Amino Acid Skeletons: Preparation of Ketomethylene Isosteres, Cory R. Theberge and Charles K. Zercher

Submissions from 2002

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Inorganic Nitrogen Losses from a Forested Ecosystem in Responseto Physical, Chemical, Biotic,and Climatic Perturbations, John D. Aber, Scott V. Ollinger, Charles T. Driscoll, Gene E. Likens, Richard T. Holmes, Rita J. Freuder, and Christine L. Goodale

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Comparison of green leaf eucalypt spectra using spectral decomposition, Nicholas C. Coops, Stephen Dury, Marie-Louise Smith, Mary E. Martin, and Scott V. Ollinger

Advancing Sensitivity for Multiply Hyphenated NMR Systems: Automated Solid Phase Extraction (LC-SPE-NMR-MS) and Capillary Scale LC-NMR, O. Corcoran, Patricia Stone Wilkinson, M. Godejohann, U. Braumann, M. Hofmann, and M. Spraul

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Electronic spectroscopy of the OH–CO reactant complex, Margaret E. Greenslade, Maria Tsiouris, R. Timothy Bonn, and Marsha I. Lester

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Synthesis, structure, and reactivity of bis(N,N′-bis(2-hydroxybenzylidene)-2-hydroxyphenylmethanediaminato)zirconium(IV), a Schiff base complex with 6,4,6-membered chelate rings, Marvin L. Illingsworth, Leslie J. Schwartz, Andrew J. Jensen, Tong Zhu, Eric J. Knappenberger, Julie E. Sweet, Patricia Stone Wilkinson, Beth E. Waltermire, and Arnold L. Rheingold

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REGIONAL VARIATION IN FOLIAR CHEMISTRY AND N CYCLING AMONG FORESTS OF DIVERSE HISTORY AND COMPOSITION, Scott V. Ollinger, Marie-Louise Smith, Mary E. Martin, Richard A. Hallett, Christine L. Goodale, and John D. Aber

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Formation of γ-Keto Esters From β-Keto Esters: Methyl 5,5-Dimethyl-4-Oxo-Hexanoate, Matthew D. Ronsheim, Ramona Hilgenkamp, and Charles K. Zercher

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Iron and Hydrogen Peroxide Detoxification Properties of Dps: A Ferritin-like DNA Binding Protein of Escherichia coli, Guanghua Zhao, Pierpaolo Ceci, Andrea Ilari, Laura Giangiacomo, Thomas M. Laue, Emilia Chiancone, and N. Dennis Chasteen

Submissions from 2001

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Assessing the performance of HYPERION in relation to eucalypt biochemistry: preliminary project design and specifications, Nicholas C. Coops, Marie-Louise Smith, Mary E. Martin, Scott V. Ollinger, A. Held, and S. J. Dury

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Tandem Chain Extension-Homoenolate Formation: The Formation of α-Methylated-γ-Keto Esters, Ramona Hilgenkamp and Charles K. Zercher

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Zinc Carbenoid-mediated Chain Extension of β-Keto Amides, Ramona Hilgenkamp and Charles K. Zercher

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Tandem Chain Extension-Aldol Reaction: Syn Selectivity with a Zinc Enolate, Sujen Lai, Charles K. Zercher, Jerry P. Jasinski, Seth N. Reid, and Richard J. Staples

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Sedimentation, Thomas M. Laue

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Electron Impact Ionization of Edge Plasma Constituents, S. Matt, T. Fiegele, G. Senn, Paul Scheier, K. Becker, H. Deutsch, Olof Echt, Aleksandar Stamatovic, and Tilmann D. Mark

“LC-NMR and LC-MS: Analysis of Six-compound Mixtures of Analogs of the Antimitotic Marine Natural Product Curacin A, P. Wipf, J. T. Reeves, and Patricia Stone Wilkinson

Submissions from 2000

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Olefin Cross-Metathesis in the Preparation of Polycyclopropanes: Formal Synthesis of FR-900848, Christopher A. Verbicky and Charles K. Zercher

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Preparation of γ-Keto Phosphonates via a Zinc-carbenoid Chain Extension Reaction, Christopher A. Verbicky and Charles K. Zercher

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Global system of rivers: Its role in organizing continental land mass and defining land‐to‐ocean linkages, Charles J. Vorosmarty, Balazs M. Fekete, M. Meybeck, and Richard B. Lammers

Submissions from 1999

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Preparation of 1,4-Dioxenes from α-Diazo-β-Keto Esters, Ramona Hilgenkamp, John B. Brogan, and Charles K. Zercher

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NMR Structure Determination of Ion Pairs Derived from Quinine:  A Model for Templating in Asymmetric Phase-Transfer Reductions by BH4- with Implications for Rational Design of Phase-Transfer Catalysts, Christine Hofstetter, Patricia Stone Wilkinson, and Thomas C. Pochapsky

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Analytical Centrifugation: Equilibrium Approach, Thomas M. Laue

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Spatial variability of climate and past atmospheric circulation patterns from central West Antarctic glaciochemistry, David B. Reusch, Paul A. Mayewski, Sallie I. Whitlow, Iqbal I. Pittalwala, and Mark S. Twickler

Submissions from 1998

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Preparation of the Zaragozic Acid Core through Rearrangement of an Oxonium Ylide, John B. Brogan and Charles K. Zercher

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Photochemical production and loss rates of ozone at Sable Island, Nova Scotia during the North Atlantic Regional Experiment (NARE) 1993 summer intensive, Katharine A. Duderstadt, M. A. Carroll, S. Sillman, T. Wang, G. M. Albercook, L. Feng, D. D. Parrish, J. S. Holloway, F. C. Fehsenfeld, Donald R. Blake, N. J. Blake, and G. Forbes

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Determining forest species composition using high spectral resolution remote sensing data, Marie Martin, Steven D. Newman, John D. Aber, and Russell G. Congalton

Submissions from 1997

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Study of the Rearrangements of Oxonium Ylides Generated from Ketals, John B. Brogan, Cary B. Bauer, Robin D. Rogers, and Charles K. Zercher

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Facile Zinc-mediated Conversion of β-Keto Esters to γ-Keto Esters, John B. Brogan and Charles K. Zercher

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Major features and forcing of high‐latitude northern hemisphere atmospheric circulation using a 110,000‐year‐long glaciochemical series, Paul A. Mayewski, L. David Meeker, Mark S. Twickler, Sallie I. Whitlow, Qinzhao Yang, W. Berry Lyons, and Michael Prentice

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Two-Directional Synthesis of Polycyclopropanes. An Approach to the Quintacyclopropane Fragment of U-106305, W. Scott McDonald, Christopher A. Verbicky, and Charles K. Zercher

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Closed-Shell Ion Pairs:  Cation and Aggregate Dynamics of Tetraalkylammonium Salts in an Ion-Pairing Solvent, Huaping Mo, Anping Wang, Patricia Stone Wilkinson, and Thomas C. Pochapsky

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Linkage between Operator Binding and Dimer to Octamer Self-Assembly of Bacteriophage λ cI Repressor†, Elena Rusinova, J. B. Alexander Ross, Thomas M. Laue, Lawrence C. Sowers, and Donald F. Senear

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Major features of glaciochemistry over the last 110,000 years in the Greenland Ice Sheet Project 2 ice core, Qinzhao Yang, Paul A. Mayewski, Mark S. Twickler, and Sallie I. Whitlow

Submissions from 1996

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Selectivity in the Rearrangements of Oxonium Ylides, John B. Brogan, Cary B. Bauer, Robin D. Rogers, and Charles K. Zercher

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Ylide-Mediated Bis-Cyclopropane Formation: A Reversal in Substrate-Mediated Facial Selectivity, Regina E. J. Cebula, Morgan R. Hanna, Cory R. Theberge, Christopher A. Verbicky, and Charles K. Zercher

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Magnetic measurements of Greenland and Himalayan ice-core samples, J. T. S. Sahota, Paul A. Mayewski, F. Oldfield, and Mark S. Twickler

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Studies on the Diastereoselective Preparation of Bicyclopropanes, Cory R. Theberge, Christopher A. Verbicky, and Charles K. Zercher

Submissions from 1995

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Preparation of Diallyl Ketals, John B. Brogan, Judson E. Richard, and Charles K. Zercher

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A Divergent Diastereoselective Approach to Bicyclopropanes, Cory R. Theberge and Charles K. Zercher

Submissions from 1994

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Diastereoselective Synthesis of Bicyclopropanes, Cory R. Theberge and Charles K. Zercher

Submissions from 1993

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Closed-shell ion pair structure and dynamics: steady-state 1H{1H}, 10B{1H}, and 11B{1H} nuclear Overhauser effects and 10B, 11B nuclear relaxation of tetraalkylammonium tetrahydridoborates in ion-pairing and dissociative solvents, Thomas C. Pochapsky, Anping Wang, and Patricia M. Stone

Submissions from 1992

The Sign of the Nuclear Overhauser Effect as a Function of Temperature in Contact Ion Pairs, Thomas C. Pochapsky, Patricia M. Stone, and E. Callagari

Submissions from 1991

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Interionic contacts in complex ion pairs detected by rotating frame nuclear Overhauser effects, Thomas C. Pochapsky, Patricia M. Stone, and Susan Sondej Pochapsky

Submissions from 1990

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Study of ion pair solution structure using nuclear overhauser effects: interionic 1H{1H} and 11B{1H} NOES in the (CH3CH2CH2CH2)4N+,BH4- ion pair, Thomas C. Pochapsky and Patricia M. Stone

Submissions from 1986

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Measurement of organic carbon in polar snow samples, Mark S. Twickler, Mary Jo Spencer, W. Berry Lyons, and Paul A. Mayewski