A Divergent Diastereoselective Approach to Bicyclopropanes
Abstract
The diastereoselective cyclopropanation of three stereoisomerically unique vinylcyclopropanes was studied. The selective preparation of six stereoisomeric bicyclopropanes was accomplished by an iterative reagent-controlled process. With the exception of the cis-syntrans-bicyclopropane, all isomers can be prepared in a diastereomeric excess of greater than 5:1.
Department
Chemistry
Publication Date
7-1-1995
Journal Title
Tetrahedron Letters
Publisher
Elsevier
Digital Object Identifier (DOI)
10.1016/0040-4039(95)01081-R
Document Type
Article
Recommended Citation
A Divergent Diastereoselective Approach to Bicyclopropanes, Theberge, C. R., Zercher, C. K., Tetrahedron Lett. 1995, 36, 5495-5498.
Rights
Copyright © 1995, Elsevier
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