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Abstract
Fires emit sufficient sulfur to affect local and regional air quality and climate. This study analyzes SO2 emission factors and variability in smoke plumes from US wildfires and agricultural fires, as well as their relationship to sulfate and hydroxymethanesulfonate (HMS) formation. Observed SO2 emission factors for various fuel types show good agreement with the latest reviews of biomass burning emission factors, producing an emission factor range of 0.47–1.2 g SO2 kg−1 C. These emission factors vary with geographic location in a way that suggests that deposition of coal burning emissions and application of sulfur-containing fertilizers likely play a role in the larger observed values, which are primarily associated with agricultural burning. A 0-D box model generally reproduces the observed trends of SO2 and total sulfate (inorganic + organic) in aging wildfire plumes. In many cases, modeled HMS is consistent with the observed organosulfur concentrations. However, a comparison of observed organosulfur and modeled HMS suggests that multiple organosulfur compounds are likely responsible for the observations but that the chemistry of these compounds yields similar production and loss rates as that of HMS, resulting in good agreement with the modeled results. We provide suggestions for constraining the organosulfur compounds observed during these flights, and we show that the chemistry of HMS can allow organosulfur to act as an S(IV) reservoir under conditions of pH > 6 and liquid water content >10−7 g sm−3. This can facilitate long-range transport of sulfur emissions, resulting in increased SO2 and eventually sulfate in transported smoke.
Department
Earth Systems Research Center
Publication Date
12-13-2022
Journal Title
Atmospheric Chemistry and Physics
Publisher
EGU
Digital Object Identifier (DOI)
Document Type
Article
Recommended Citation
Rickly, P. S., H. Guo, P. Campuzano-Jost, J. L. Jimenez, G. M. Wolfe, R. Bennett, I. Bourgeois, J. D. Crounse, J. E. Dibb, J. P. DiGangi, G. S. Diskin, M. Dollner, E. M. Gargulinski, S. R. Hall, H. S. Halliday, T. F. Hanisco, R. A. Hannun, J. Liao, R. Moore, B. A. Nault, J. B. Nowak, J. Peischl, C. E. Robinson, T. Ryerson, K. J. Sanchez, M. Schöberl, A. J. Soja, J. M. St. Clair, K. L. Thornhill, K. Ullmann, P. O. Wennberg, B. Weinzierl, E. B. Wiggins, E. L. Winstead, and A. W. Rollins (2022) Emission factors and evolution of SO2 measured from biomass burning in wild and agricultural fires, Atmospheric Chemistry and Physics, 22, 15603-15620, https://doi.org/10.5194/acp-22-15603-2022.
Rights
© The Author(s) 2022
Comments
This is an open access article published by EGU in Atmospheric Chemistry and Physics in 2022, available online: https://doi.org/10.5194/acp-22-15603-2022