Date of Award

Winter 1979

Project Type

Dissertation

Program or Major

Chemistry

Degree Name

Doctor of Philosophy

Abstract

Copper(II) complexes of the carboxylate anions of L-(-)-proline, pipecolinic acid, picolinic acid, anthranilic acid, 4-chloro-anthranilic acid, 3,5-dichloro-anthranilic acid, N-phenyl-anthranilic acid, and flufenamic acid were prepared and characterized by thermal gravimetric analysis, differential scanning calorimetry, X-ray diffraction, infrared and visible spectroscopy, magnetic susceptibility, and electron paramagnetic resonance spectroscopy. Copper-doped nickel(II) and zinc(II) complexes were also prepared. The EPR spectra were examined in detail. The N-phenyl-anthranilate and flufenamate complexes are dimeric. Zero field splitting parameters are reported.

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