Krypton Dimers: Resonance-Enhanced MPI via Gerade States in the Region of Atomic 4p55p Configurations
The two‐photon resonant absorption of Kr2(1Σ+g) has been measured via (2+1) multiphoton ionization studies in the energy range 91 750–92 420 cm−1. Two vibrational progressions are observed. One of them is attributed to the atomic 4p5(2P3/2)5p[5/2]2 state, implying D’0 =220 cm−1. A long progression is assigned as correlating with the 4p5(2P3/2)5p[3/2]2 state, implying D0 ≥1480 cm−1.
The Journal of Chemical Physics
Digital Object Identifier (DOI)
O. Echt, M. C. Cook and A. W. Castleman, Jr., Krypton Dimers: Resonance-Enhanced MPI via Gerade States in the Region of Atomic 4p55p Configurations, J. Chem. Phys. 87 (1987) 3276 – 3280, DOI: 10.1063/1.453020.