We derive tropospheric column BrO during the ARCTAS and ARCPAC field campaigns in spring 2008 using retrievals of total column BrO from the satellite UV nadir sensors OMI and GOME-2 using a radiative transfer model and stratospheric column BrO from a photochemical simulation. We conduct a comprehensive comparison of satellite-derived tropospheric BrO column to aircraft in-situ observations of BrO and related species. The aircraft profiles reveal that tropospheric BrO, when present during April 2008, was distributed over a broad range of altitudes rather than being confined to the planetary boundary layer (PBL). Perturbations to the total column resulting from tropospheric BrO are the same magnitude as perturbations due to longitudinal variations in the stratospheric component, so proper accounting of the stratospheric signal is essential for accurate determination of satellite-derived tropospheric BrO. We find reasonably good agreement between satellite-derived tropospheric BrO and columns found using aircraft in-situ BrO profiles, particularly when satellite radiances were obtained over bright surfaces (albedo >0.7), for solar zenith angle
Atmospheric Chemistry and Physics
Digital Object Identifier (DOI)
Choi, S., Wang, Y., Salawitch, R. J., Canty, T., Joiner, J., Zeng, T., Kurosu, T. P., Chance, K., Richter, A., Huey, L. G., Liao, J., Neuman, J. A., Nowak, J. B., Dibb, J. E., Weinheimer, A. J., Diskin, G., Ryerson, T. B., da Silva, A., Curry, J., Kinnison, D., Tilmes, S., and Levelt, P. F.: Analysis of satellite-derived Arctic tropospheric BrO columns in conjunction with aircraft measurements during ARCTAS and ARCPAC, Atmos. Chem. Phys., 12, 1255-1285, doi:10.5194/acp-12-1255-2012, 2012.
© Author(s) 2012. This work is distributed under the Creative Commons Attribution 3.0 License.